Oak Ridge National Laboratory

OAK RIDGE — Chemists at the Department of Energy’s Oak Ridge National Laboratory have invented a more efficient way to extract lithium from waste liquids leached from mining sites, oil fields and used batteries. They demonstrated that a common mineral can adsorb at least five times more lithium than can be collected using previously developed adsorbent materials. 

“It’s a low-cost, high-lithium-uptake process,” said Parans Paranthaman, an ORNL Corporate Fellow and National Academy of Inventors Fellow with 58 issued patents. He led the proof-of-concept experiment with Jayanthi Kumar, an ORNL materials chemist with expertise in the design, synthesis and characterization of layered materials.

“The key advantage is that it works in a wider pH range of 5 to 11 compared to other direct lithium extraction methods,” Paranthaman said. The acid-free extraction process takes place at 140 degrees Celsius, compared to traditional methods that roast mined minerals at 250 degrees Celsius with acid or 800 to 1,000 degrees Celsius without acid.

Lithium is a lightweight metal commonly used in energy-dense and rechargeable batteries. Electric vehicles, which are needed to achieve net-zero emissions by 2050, rely on lithium-ion batteries. Industrially, lithium is extracted from brines, rocks and clays. The ORNL innovation may help meet rising demand for lithium by making domestic sources commercially viable.